Yes, it always happens. Every angle of symmetry of a figure is a multiple of its smallest angle of symmetry.
Exactly 3 angles: 120°, 240°, 360° → multiples of 120
Exactly 4 angles: 90°, 180°, 270°, 360° → multiples of 90
Since the full turn 360° is always an angle of symmetry, the smallest angle s must divide 360 exactly. That is why the order of rotational symmetry is always a factor of 360 when s is a whole number of degrees.