No — all four are rectangles, including (iv).
| Figure | Sides | All angles 90°? | Rectangle? |
|---|---|---|---|
| (i) | 5 cm, 2 cm, 5 cm, 2 cm | Yes | Yes |
| (ii) | 3.6 cm, 6 cm, 3.6 cm, 6 cm | Yes | Yes |
| (iii) | 5 cm, 1 cm, 5 cm, 1 cm | Yes | Yes |
| (iv) | 4 cm, 4 cm, 4 cm, 4 cm | Yes | Yes — and also a square |
Every one of the four figures carries a right-angle mark at all four corners, and that is the only thing the definition asks for. Being tilted on the page (as (ii) and (iii) are) changes nothing — angles do not depend on how a figure is turned.
Square: a quadrilateral in which all the angles are equal to 90°, and all the sides are of equal length.