Because the two faces of the puri do not set at the same instant. The face that hardens first can no longer stretch; the face that is still soft is the one the steam pushes out, so it spreads over a larger area and becomes thin.
Follow what happens inside the puri:
- The rolled disc holds water bound in the dough.
- Hot oil is at roughly 180 °C, far above the boiling point of water. Within a second or two the outer surface of the disc dries and stiffens into a thin, sealed crust.
- Under that crust the water flashes into steam. The same water needs more than a thousand times as much room as steam, so the pressure inside shoots up.
- The dough underneath is still soft and stretchy, so instead of bursting it splits into two layers and balloons out.
- The layer that met the oil first — the one we also hold down with the slotted spoon — has already stiffened, so it stretches very little. The other layer is still soft, gives way, and stretches. The same amount of dough spread over a bigger area must be thinner.