How to do it. Just after sunset (for a waxing crescent) stand where you can see both the glow of the Sun near the western horizon and the crescent. Point one finger at the Sun, then sweep it along the shortest path in the sky to the Moon. Never look straight at the Sun — point at it, do not stare at it.
What you will find. Every single time, the finger reaches the bright edge of the crescent before it reaches the dark part. The bulging outer edge of the crescent is always turned Sunward.
The line joining the tips. The two tips of a crescent are the points where the light–dark boundary meets the Moon's rim. That boundary is a great circle running round the Moon through its poles, so its two visible ends are always at opposite points of the rim — and the line joining opposite points of a circle is a diameter. Measuring across the horns therefore measures the full width of the Moon, however thin the crescent is.